Effect of preparation method on physicochemical properties and catalytic performances of LaCoO_3 perovskite for CO oxidation

Perovskite oxides LaCoO_3 prepared by templating, co-precipitation and sol-gel method with different complexants were systematically characterized and its catalytic performances for CO oxidation were investigated. The samples were characterized by X-ray diffraction, thermogravimetry analysis and differential scanning calorimetry, N_2 physisorption, transmission electron microscopy, temperature program reduction of hydrogen, temperature program desorption of oxygen and X-ray photoelectron spectroscopy measurement, results of which show that the properties of LaCoO_3, such as surface morphology, surface area, surface compositions, redox capability, oxygen vacancy, as well as the calcination temperature and formation mechanism, depend intimately on the preparation method. Catalytic tests indicate that the sample prepared by carbon templating method shows the best activity for CO oxidation, with full CO conversion obtained at 135 ℃. In particular, the catalyst can be activated and significant increase of activity can be obtained with the increase of reaction time. The cyclic and longterm stability of catalysts were discussed and compared.     

准噶尔盆地吉木萨尔凹陷陆相页岩油地质特征与聚集机理

综合利用岩心、测井、烃源岩热解、铸体薄片、场发射扫描电镜、激光共聚焦显微镜与高压压汞等分析测试的结果，对准噶尔盆地吉木萨尔凹陷芦草沟组陆相页岩油地质特征与聚集机理进行了研究。结果表明：吉木萨尔凹陷咸化湖盆型沉积地层富含有机质，是烃源岩层也是储层，页岩油藏具有“源储一体”的地质特征，存在粉砂岩类与泥岩类和白云岩类与泥岩类两类岩性组合类型。芦草沟组大面积整体含油、“甜点”富集且原油成熟度较低。页岩油赋存岩石的润湿性为亲油性，生烃增压是页岩油运聚的主要动力。微纳米孔喉、层理缝与构造裂缝形成页岩油的有利储集空间与渗流通道。页岩油整体为源内或近源聚集，并以游离态和吸附态赋存于芦草沟组“甜点”段与泥页岩层段中。     

A Generalized Cubemap for Encoding 360° VR Videos using Polynomial Approximation

360^° VR videos provide users with an immersive visual experience. To encode 360^° VR videos, spherical pixels must be mapped onto a two‐dimensional domain to take advantage of the existing video encoding and storage standards. In VR industry, standard cubemap projection is the most widely used projection method for encoding 360^° VR videos. However, it exhibits pixel density variation at different regions due to projection distortion. We present a generalized algorithm to improve the efficiency of cubemap projection using polynomial approximation. In our algorithm, standard cubemap projection can be regarded as a special form with 1st‐order polynomial. Our experiments show that the generalized cubemap projection can significantly reduce the projection distortion using higher order polynomials. As a result, pixel distribution can be well balanced in the resulting 360^° VR videos. We use PSNR, S‐PSNR and CPP‐PSNR to evaluate the visual quality and the experimental results demonstrate promising performance improvement against standard cubemap projection and Google's equi‐angular cubemap.     

Selective clustering for representative paintings selection

Multimedia Tools and Applications - Selective classification (or rejection based classification) has been proved useful in many applications. In this paper we describe a selective clustering...     

某企业不同工种的放射工作人员发生甲状腺结节风险分析

采用职业健康体检资料和问卷形式,利用单因素和多因素logistic回归模型,分析探讨某企业内不同工种的放射工作人员暴露在低剂量电离辐射环境下发生甲状腺结节的风险。结果表明,放射工作人员中以混合射线组甲状腺结节发生风险最高,随着年龄和放射工龄的增加发生风险会增加;性别不同与甲状腺结节发生风险有关。     

A delay coupling method to reduce the dynamical degradation of digital chaotic maps and its application for image encryption

Multimedia Tools and Applications - In this study, a novel delayed coupled chaotic model to reduce the dynamical degradation of digital chaotic maps is firstly proposed. In this model, we introduce...     

利用地震品质因子Q比例的分布特征预测南川页岩气藏保存条件

根据地震数据、地质资料和地震属性，开展了南川地区五峰组-龙马溪组下部页岩的地震品质因子Q平面上分布与页岩气保存条件评价研究。针对南川地区页岩气开发中的断裂破碎带，提出了一种获取稳定品质因子Q比例及界限的工作流程和相应的迭代算法。研究表明，地震品质因子Q比例的分布可以快速、直观识别出断裂破碎带的内幕特征与不同类型页岩分布区。其中，断裂破碎带页岩区的品质因子Q比例总体上偏小，大多低于0.2，局部超过0.5，平面上分布杂乱、碎斑状；页岩呈北东向展布的条带，被断裂所撕裂、破碎，保存条件较差。稳定分布的页岩区的品质因子Q比例是较高的，超过0.7，平面变化稳定，没有突变现象，保存条件好。微裂缝发育的页岩区的品质因子Q比例具有渐变的趋势性，品质因子Q比例的分布从该页岩区的边部0.7向中部有规律地减小至0.1，保存条件最佳。实践证明，高产气井大多位于稳定分布的页岩区或内部微裂隙发育的稳定页岩区，地震品质因子Q比例研究方法对页岩气保存评价与开发井优化部署是一个实用工具。     

Beam and image experiment of beam deflection electron gun for distributed X-ray sources

Distributed X-ray sources comprise a single vacuum chamber containing multiple X-ray sources that are triggered and emit X-rays at a specific time and location. This process facilitates an application for innovative system concepts in X-ray and computer tomography. This paper proposes a novel electron beam focusing, shaping,and deflection electron gun for distributed X-ray sources.The electron gun uses a dispenser cathode as an electron emitter, a mesh grid to control emission current, and two electrostatic lenses for beam shaping, focusing, and deflection. Novel focusing and deflecting electrodes were designed to increase the number of focal spots in the distributed source. Two identical half-rectangle opening electrodes are controlled by adjusting the potential of the two electrodes to control the electron beam trajectory, and then, multifocal spots are obtained on the anode target. The electron gun can increase the spatial density of the distributed X-ray sources, thereby improving the image quality. The beam experimental results show that the focal spot sizes of the deflected(deflected amplitude 10.5 mm)and non-deflected electron beams at full width at half maximum are 0.80 mm 90.50 mm and 0.55 mm 90.40 mm, respectively(anode voltage 160 kV; beam current 30 mA). The imaging experimental results demonstrate the excellent spatial resolution and time resolution of an imaging system built with the sources, which has an excellent imaging effect on a field-programmable gate array chip and a rotating metal disk.     

Optimal parameter choice of CR–RC~m digital filter in nuclear pulse processing

CR–RC~m filters are widely used in nuclear energy spectrum measurement systems. The choice of parameters of a CR–RC~m digital filter directly affects its performance in terms of energy resolution and pulse count rate in digital nuclear spectrometer systems. A numerical recursive model of a CR differential circuit and RC integration circuit is derived, which shows that the shaping result of CR–RC~m is determined by the adjustment parameter(k, it determines the shaping time of the shaper)and the integral number(m). Furthermore, the amplitude–frequency response of CR–RC~m is analyzed, which shows that it is a bandpass filter; the larger the shaping parameters(k and m), the narrower is the frequency band. CR–RC~m digital Gaussian shaping is performed on the actual sampled nuclear pulse signal under different shaping parameters. The energy spectrum of ~(137)Cs is measured based on the LaBr_3(Ce) detector under different parameters. The results show that the larger the shaping parameters(m and k), the closer the shaping result is to Gaussian shape, the wider is the shaped pulse, the higher is the energy resolution, and the lower is the pulse count rate. For the same batch of pulse signals, the energy resolution is increased from 3.8 to 3.5%, and the full energy peak area is reduced from 7815 to 6503. Thus, the optimal shaping parameters are m=3 and k=0:95. These research results can provide a design reference for the development of digital nuclear spectrometer measurement systems.     

数字模拟和USS通信电气组态试验箱设计

电气组态技术主要包括数字控制、模拟量控制、通信协议控制三种。本文设计了一种可以实现西门子S7-200系列PLC之间,及PLC和MM420变频器之间数字、模拟、通信控制三种实验,配合MCGS触摸屏显示效果的教学试验箱。学生可以在此试验箱上通过变频参数设置、 PLC程序设计、 MCGS触摸屏界面开发、电气电路选配,完成自动化组态技术中数字、模拟、通信协议控制的所有实验和技术操作。